Author/Authors :
Gale ، نويسنده , , G.M and Gallot، نويسنده , , G and Lascoux، نويسنده , , N، نويسنده ,
Abstract :
The vibrational population relaxation time has been measured across the inhomogeneously broadened OH stretching mode (ν3) of a 0.5% solution of HDO in D2O. Relaxation times vary from 0.5 ps at low frequency (3270 cm−1) to 1.0 ps at high frequency (3600 cm−1). This variation is attributed to a V–V transfer mechanism between ν3 and 2ν2.