Title of article
On the capacity of liquid-liquid interfaces
Author/Authors
Pereira، نويسنده , , C.M. and Schmickler، نويسنده , , W. and Silva، نويسنده , , A.F. and Sousa، نويسنده , , M.J.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1997
Pages
8
From page
13
To page
20
Abstract
The differential capacity of a large number of liquid-liquid interfaces has been determined by impedance spectroscopy. Even in the absence of ion pairing, the interfacial capacity was always larger than predicted by Gouy-Chapman theory. These findings are explained within a simple model, in which an extended mixed-boundary layer exists at the interface, whose thickness extends over several solvent diameters.
Journal title
Chemical Physics Letters
Serial Year
1997
Journal title
Chemical Physics Letters
Record number
1780179
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