Author/Authors :
Okabe، نويسنده , , Chie and Tanaka، نويسنده , , Nobuyuki and Fukaminato، نويسنده , , Tuyoshi and Kawai، نويسنده , , Tsuyoshi and Irie، نويسنده , , Masahiro and Nibu، نويسنده , , Yoshinori and Shimada، نويسنده , , Hiroko and Goldberg، نويسنده , , Alexander and Nakamura، نويسنده , , Shinichiro and Sekiya، نويسنده , , Hiroshi، نويسنده ,
Abstract :
Photochromic reaction of 1,2-bis(3-methyl-2-thienyl)perfluorocyclopentene has been studied by FT-Raman spectroscopy. The Raman bands in the 1300–1700 cm−1 region of the open-ring isomer of 1,2-bis(3-methyl-2-thienyl)perfluorocyclopentene are clearly distinguished from those of the closed-ring isomer. The vibrational assignment has been made by measuring the polarized Raman spectrum and density functional theory calculations at the B3LYP/6-31G** level.