Author/Authors :
Ohmori، نويسنده , , K. and Kurosawa، نويسنده , , T. and Chiba، نويسنده , , H. and Okunishi، نويسنده , , M. and Sato، نويسنده , , Y. and Devdariani، نويسنده , , A.Z. and Nikitin، نويسنده , , E.E.، نويسنده ,
Abstract :
We have measured the c̃–X̃ laser excitation spectra of the Hg–N2 and CO collisional quasimolecules for the formation of Hg(63P2) and Hg(63P1) in the far wings of the Hg 61S0–63P2 dipole-forbidden line. These are the first observations of the c̃–X̃ bands in Hg–molecule systems. It is found that Hg(63P1) is efficiently produced via a nonadiabatic transition from the c̃ state. This is in striking contrast with the Hg–rare gas cases where no nonadiabatic processes have been observed.
