Author/Authors :
Simard، نويسنده , , Benoit and Dénommée، نويسنده , , Stéphane and Rayner، نويسنده , , David M. and Heijnsbergen، نويسنده , , Deniz van and Meijer، نويسنده , , Gerard and Helden، نويسنده , , Gert von، نويسنده ,
Abstract :
Free electron laser IR photodepletion spectroscopy of metal cluster–ligand complexes in a molecular beam is demonstrated on Agn(NH3)m complexes in the range 800–1150 cm−1. Where direct comparison can be made, our spectra agree with spectra measured by CO2 laser photodepletion spectroscopy. New vibrational spectroscopic data addressing previously unreachable spectral regions, including results for deuterated ND3 are reported for complexes of Ag3, Ag4 and Ag5.
