Author/Authors :
Andreas and Gِdicke، نويسنده , , Bjِrn and Langenscheidt، نويسنده , , Andreas and Meyer، نويسنده , , Hermann and Schweig، نويسنده , , Armin، نويسنده ,
Abstract :
Persistent contact ion pairs (CIPs) have been obtained by one-photon-induced electron transfer from N,N,N′,N′-tetramethyl-p-phenylenediamine (TMPD) to tetrachloromethane (CCl4) in solid argon, in addition to TMPD⋅+ free radical cations (FRCs) generated by two-photon ionization of TMPD as the primary process. The first UV/VIS absorption band of the CIPs is tentatively explained on the basis of the corresponding band of the FRCs.
