Title of article
On the Dirac–Frenkel/McLachlan variational principle
Author/Authors
Raab، نويسنده , , A.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
5
From page
674
To page
678
Abstract
The Dirac–Frenkel/McLachlan variational principle (DFMVP) is re-derived using a general and strict formalism which is valid for all practical applications. General equations of motion for the parameters are derived from the DFMVP. The time-dependent parameter set solving the equations of motion forms an approximate variational solution of the original problem. An error estimate for the approximation is presented which shows that the variational solution converges to the exact one if the parametrisation is improved.
Journal title
Chemical Physics Letters
Serial Year
2000
Journal title
Chemical Physics Letters
Record number
1781815
Link To Document