Title of article :
On the Dirac–Frenkel/McLachlan variational principle
Author/Authors :
Raab، نويسنده , , A.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2000
Abstract :
The Dirac–Frenkel/McLachlan variational principle (DFMVP) is re-derived using a general and strict formalism which is valid for all practical applications. General equations of motion for the parameters are derived from the DFMVP. The time-dependent parameter set solving the equations of motion forms an approximate variational solution of the original problem. An error estimate for the approximation is presented which shows that the variational solution converges to the exact one if the parametrisation is improved.
Journal title :
Chemical Physics Letters
Journal title :
Chemical Physics Letters