Title of article
Photochemistry of chloropicrin in cryogenic matrices
Author/Authors
Wade، نويسنده , , Elisabeth A and Reak، نويسنده , , Kristina E and Parsons، نويسنده , , Bradley F and Clemes، نويسنده , , Thomas P and Singmaster، نويسنده , , Karen A، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
7
From page
473
To page
479
Abstract
The photolysis of chloropicrin (CCl3NO2) was investigated in Ar and N2 cryogenic matrices. The extent of reaction was monitored using FT-IR spectroscopy. Phosgene and nitrosyl chloride were the observed photoproducts at all wavelengths investigated (220, 251, 313, 365, and 405 nm). When the photolysis was performed with 220, 251, or 313 nm light, two additional bands were also observed. These bands have been assigned to CCl3ONO. Chloropicrin was also photolyzed in the presence of O2 and 18O2. 18O-labeled photoproducts were not detected in cryogenic matrices.
Journal title
Chemical Physics Letters
Serial Year
2002
Journal title
Chemical Physics Letters
Record number
1782401
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