Author/Authors :
Xie، نويسنده , , Jingli and Ren، نويسنده , , Xiaoming and He، نويسنده , , Cheng and Song، نويسنده , , You and Meng، نويسنده , , Qingjin and Kremer، نويسنده , , R.K. and Yao، نويسنده , , Yuangen، نويسنده ,
Abstract :
A new ion-pair complex [1-(4′-cyanobenzyl)pyridinium] [Ni(mnt)2] (1), in which mnt2−=maleonitriledithiolate, have been fabricated and its X-ray single crystal structural analyses at 293, 180 and 140 K shown that the [Ni(mnt)2]− anions and [CNBzPy]+ cations form a well-separated stacking column along c-axis direction, within which [Ni(mnt)2]− anions are uniformly spaced to give a one-dimensional (1-D) chain structure. Bulk magnetic properties of this complex have been investigated in the temperature range of 2–400 K and shown there exists spin kink at ∼190 K. In low temperature region, weak ferromagnetic behavior occurs in 1.
