• Title of article

    The reaction of formaldehyde with chlorine atom

  • Author/Authors

    Dong، نويسنده , , Feng and Qu، نويسنده , , Zhengwang and Zhang، نويسنده , , Qiyuan and Kong، نويسنده , , Fanao، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    6
  • From page
    29
  • To page
    34
  • Abstract
    The elementary reaction of formaldehyde (H2CO) with chlorine atom has been experimentally investigated by the time-resolved infrared emission spectroscopy. The nascent products HCO and HCl (v⩽3) are observed. The major product channel has been identified as Cl+H2CO→HCl+HCO. Theoretical calculations have revealed that the mechanism is a nearly barrierless peripheral hydrogen abstraction reaction.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    2003
  • Journal title
    Chemical Physics Letters
  • Record number

    1783460