Author/Authors :
Farantos، نويسنده , , S.C and Filippou، نويسنده , , E and Stamatiadis، نويسنده , , S and Froudakis، نويسنده , , G.E and Mühlhنuser، نويسنده , , M and Peric، نويسنده , , Massaouti، نويسنده , , M and Sfounis، نويسنده , , A and Velegrakis، نويسنده , , M، نويسنده ,
Abstract :
The first absorption band in the photofragmentation spectroscopy of Sr+CO, is recorded in the energy region between 15 600 and 16 200 cm−1. The spectrum is characterized by a sharp peak between two zones with broad peaks. In contrast to this, the second absorption band observed in the energy interval of 19 000–23 000 cm−1 shows a regular vibrational structure accompanied by a low intensity shoulder which covers the energy up to the dissociation. Electronic multi-reference configuration interaction calculations in the 2-D nuclear configuration space with the CO bond frozen provide a qualitative explanation of the spectra.