Author/Authors :
Sailer، نويسنده , , W. and Pelc، نويسنده , , A. and Limمo-Vieira، نويسنده , , P. and Mason، نويسنده , , N.J. and Limtrakul، نويسنده , , J. and Scheier، نويسنده , , P. and Probst، نويسنده , , M. and Mنrk، نويسنده , , T.D.، نويسنده ,
Abstract :
Low energy electron attachment cross sections for acetonitrile (CH3CN) are reported in the energy range from about 0 up to 10 eV determined with an energy resolution of 140 meV. Electron attachment is shown to be a purely dissociative process with the production of the five anionic fragments: CH2CN−, CHCN−, CCN−, CN− and CH3− observed in two energy regions, the first between 1 and 4 eV, the second in excess of 6 eV. Quantum chemical and trajectory calculations have been carried out to complement the experimental results.
