• Title of article

    Spectroscopic and structural study of Y2C2 carbide encapsulating endohedral metallofullerene: (Y2C2)@C82

  • Author/Authors

    Inoue، نويسنده , , Takashi and Tomiyama، نويسنده , , Tetsuo and Sugai، نويسنده , , Toshiki and Shinohara، نويسنده , , Hisanori، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    6
  • From page
    226
  • To page
    231
  • Abstract
    The first di-yttrium carbide endohedral metallofullerene has been produced and spectroscopically and structurally characterized. 13C NMR structural analyses reveal that di-yttrium endohedral metallofullerene having a molecular formula of Y2C84 has been found to possess an endohedral yttrium carbide structure, (Y2C2)@C82, in which a Y2C2 species is encaged by a C82-C3v(8) fullerene. The encaged Y2C2 species should rapidly rotate in order to maintain the entire (Y2C2)@C82 molecular symmetry unchanged at room temperature.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    2003
  • Journal title
    Chemical Physics Letters
  • Record number

    1784489