Author/Authors :
Huijuan، نويسنده , , Che and Huimin، نويسنده , , Bi and Rui، نويسنده , , Ding and Dong، نويسنده , , Wang and Lingpeng، نويسنده , , Meng and Shijun، نويسنده , , Zheng and Dianxun، نويسنده , , Wang and Mok، نويسنده , , Daniel Kam-Wak and Chau، نويسنده , , Foo-Tim، نويسنده ,
Abstract :
The continuous flowing beams of the triplet state phenylnitrene (PhN) species have been generated by respective pyrolysis of PhN3 at 83(±0.5) °C and phenylisocyanate (PhNCO) at 105(±0.5) °C in the quartz inlet tube loosely filled with a 30 إ molecular sieve powder supported on the quartz wool. PE spectrum of PhN is recorded in situ for the first time. The ionization energies, corresponding to different ionic states of PhN+, are determined by PES experiment and both G2 and DFT calculations. The study indicates that PhN is a diradical with C2v symmetry and has a 3A2 ground state.
