Author/Authors :
Wodtke، نويسنده , , Alec M. and Hansen، نويسنده , , Nils and Robinson، نويسنده , , Jason C. and Sveum، نويسنده , , Niels E. and Goncher، نويسنده , , Scott J. and Neumark، نويسنده , , Daniel M.، نويسنده ,
Abstract :
The primary reaction products from 248-nm chlorine azide photolysis are identified in a collision-free experiment. In contrast to all previous reports, the radical channel producing Cl + N3 (95 ± 3%) is seen to dominate the photochemistry. The molecular channel producing NCl + N2 (5 ± 3%) was also observed.
