Title of article
Solid state kinetics of the oxidation of MoO2 investigated by time-resolved X-ray absorption spectroscopy
Author/Authors
Ressler، نويسنده , , T and Wienold، نويسنده , , J and Jentoft، نويسنده , , R.E and Timpe، نويسنده , , O and Neisius، نويسنده , , T، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
6
From page
169
To page
174
Abstract
The isothermal oxidation of MoO2 in oxygen (100%) at temperatures between 623 K and 823 K is studied by time-resolved in situ X-ray absorption spectroscopy. Four rate-determining steps (i.e. mass transport, boundary control, nuclei growth, and diffusion) dependent on temperature and the extent of reaction are found to govern the rapid oxidation of MoO2. The XANES and EXAFS results presented show that time-resolved XAFS studies can be used to investigate rapid solid-state reactions and to elucidate kinetics and structural evolution of the constituent phases.
Keywords
C. EXAFS , E. Atom , E. X-ray absorption spectroscopy
Journal title
Solid State Communications
Serial Year
2001
Journal title
Solid State Communications
Record number
1786965
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