Title of article
Crystal and electronic structure and physical properties of Ni5P4
Author/Authors
Babizhetskyy، نويسنده , , V. and Kotur، نويسنده , , B. and Oryshchyn، نويسنده , , S. and Zheng، نويسنده , , C. and Kneidinger، نويسنده , , F. and Leber، نويسنده , , L. and Simson، نويسنده , , C. and Bauer، نويسنده , , E. and Michor، نويسنده , , H.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
5
From page
1
To page
5
Abstract
Ni5P4 crystallizes in hexagonal symmetry, space group P63mc, and adopts its own non-centrosymmetric structure type with lattice constants a=6.78982(4), c=10.98679(7) Å according to x-ray powder diffraction. Calorimetric, magnetic and transport studies of Ni5P4 reveal a Pauli-paramagnetic, normal metallic behavior down to 380 mK. The experimental value of the electronic Sommerfeld coefficient γ=13.2 mJ/(mol K2) as well as ab initio electronic structure calculations indicate a moderate electronic density of states at the Fermi level situated near the upper edge of essentially filled d-bands.
Keywords
A. Binary nickel–phosphorus compound , D. Magnetic behavior , D. Electrical resistivity , D. Specific heat
Journal title
Solid State Communications
Serial Year
2013
Journal title
Solid State Communications
Record number
1794219
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