Title of article :
Thermodynamic assessment of the La–Mg system
Author/Authors :
Berche، نويسنده , , A. and Benigni، نويسنده , , P. and Rogez، نويسنده , , J. and Record، نويسنده , , M.-C.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2011
Abstract :
A thermodynamic modeling and optimization of the La–Mg system is carried out by means of the CALPHAD method taking into account the latest experimental results. The liquid, bcc-La, fcc-La, dhcp-La and hcp-Mg solutions are modeled as substitutional solutions (La, Mg) using the Redlich–Kister formalism. The LaMg, LaMg2, La5Mg41, La2Mg17 and LaMg12 phases are treated as stoichiometric compounds, and the non-stoichiometry of LaMg3 is described as (La,Mg)0.25Mg0.75. The results are in good agreement with the set of experimental data which were carefully discussed and selected.
Keywords :
Magnesium , Thermodynamic assessment , lanthanum , CALPHAD method
