Title of article :
A selective catalytic side chain oxidation of lysine and ornithine derivatives
Author/Authors :
Rossen، نويسنده , , Kai and Kolarovi?، نويسنده , , Andrej and Baskakov، نويسنده , , Denys and Kiesel، نويسنده , , Michael، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
The fully protected derivatives of the diamino acids lysine and ornithine (n=1, 2) can be oxidized selectively in the side chain using a Mn(OAc)2/peracetic acid/NaOAc system. The ε or γ carbon, respectively, is converted to the aldehyde oxidation state, protected as the cyclic N,N-acetal.
Keywords :
amino aldehydes , Catalysis , amino acids and derivatives , cyclization , manganese and compounds , Oxidation , piperidines
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
