Title of article
A selective catalytic side chain oxidation of lysine and ornithine derivatives
Author/Authors
Rossen، نويسنده , , Kai and Kolarovi?، نويسنده , , Andrej and Baskakov، نويسنده , , Denys and Kiesel، نويسنده , , Michael، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
3
From page
3023
To page
3025
Abstract
The fully protected derivatives of the diamino acids lysine and ornithine (n=1, 2) can be oxidized selectively in the side chain using a Mn(OAc)2/peracetic acid/NaOAc system. The ε or γ carbon, respectively, is converted to the aldehyde oxidation state, protected as the cyclic N,N-acetal.
Keywords
amino aldehydes , Catalysis , amino acids and derivatives , cyclization , manganese and compounds , Oxidation , piperidines
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1841240
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