Title of article :
Radical deoxygenation of tertiary alcohols via trifluoroacetates
Author/Authors :
Kim، نويسنده , , Joonggon and Cho، نويسنده , , Dae Hyan and Jang، نويسنده , , Doo Ok، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
Trifluoroacetates of tertiary alcohols undergo deoxygenation by Ph2SiH2 in the presence of (tBuO)2 in excellent yields of the deoxy products without affecting the stereochemistry at β-carbon.
Keywords :
deoxygenation , trifluoroacetate , radical , tert-alcohol
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters