Title of article :
Direct allylic substitution of allyl alcohols by carbon pronucleophiles in the presence of a palladium/carboxylic acid catalyst under neat conditions
Author/Authors :
Patil، نويسنده , , Nitin T. and Yamamoto، نويسنده , , Yoshinori، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
The reaction of allylic alcohols with carbon pronucleophiles in the presence of the Pd(PPh3)4/carboxylic acid combined catalytic system, under neat conditions (without an organic solvent or without water as the solvent) enabled the direct allylation of the pronucleophiles, giving the corresponding allylated products in high yields.
Keywords :
palladium catalyst , allylic substitution , ?-allylpalladium complex , Pronucleophile , water , Palladium carboxylic acid catalyst , Allylic alcohol
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters