Title of article :
Rhodium-catalyzed carbonylation of 2-alkynylbenzylamine: a new route to the synthesis of benzazepinones
Author/Authors :
Shiba، نويسنده , , Takanori and Zhou، نويسنده , , Da-Yang and Onitsuka، نويسنده , , Kiyotaka and Takahashi، نويسنده , , Shigetoshi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
Rhodium-catalyzed carbonylation of 2-alkynylbenzylamines under water–gas shift reaction conditions gives a seven-membered heterocyclic product, 2,4-disubstituted-1,4-dihydrobenz[c]azepin-3-ones, in a good yield.
Keywords :
carbonylation , Alkynylbenzylamine , Rhodium catalyst , Water–gas shift reaction , Benzazepinone , heterocycle
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters