Title of article
Preparation and characterization of diphenylboron cation in solution
Author/Authors
Uddin، نويسنده , , Md.Khabir and Fujiyama، نويسنده , , Ryoji and Kiyooka، نويسنده , , Syun-ichi and Fujio، نويسنده , , Mizue and Tsuno، نويسنده , , Yuho، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
3913
To page
3916
Abstract
The electrophilic abstraction of chloride ion by SbCl5 from diphenylchloroborane in CD3NO2 resulted in a transient species of which 11B NMR chemical shift appeared at 20 ppm. This was indicative of diphenylboron cation, stabilized with electron donor O-atom of two nitromethane molecules. The experimental 11B chemical shift for the solvated diphenylboron cation is in good agreement with that calculated by GIAO-HF/6-311+G(2d,p)//B3LYP/6-31+G(d).
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1841600
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