Title of article :
Synthesis and catalytic activity of a fluorous-tagged TEMPO radical
Author/Authors :
Pozzi، نويسنده , , Gianluca and Cavazzini، نويسنده , , Marco and Holczknecht، نويسنده , , Orsolya and Quici، نويسنده , , Silvio and Shepperson، نويسنده , , Ian، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
A fluorous-tagged TEMPO radical has been prepared and its catalytic activity in the chemoselective oxidation of alcohols to carbonyl compounds has been investigated. The new fluorous radical proved to be an efficient, selective and easily recoverable catalyst, which can be conveniently used in standard organic solvents and then isolated and recycled by fluorous liquid–liquid extraction.
Keywords :
alcohols , Biphasic catalysis , Oxidation , ketones , Aldehydes
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters