Title of article :
Radical-chain functionalisation at C–H centres using an O-oxiranylcarbinyl O-silyl ketene acetal
Author/Authors :
Cai، نويسنده , , Yudong and Dang، نويسنده , , Hai-Shan and Roberts، نويسنده , , Brian P.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
A readily prepared O-oxiranylcarbinyl O-silyl ketene acetal has been used to bring about functionalisation at various types of saturated C–H group, through the intermediacy of an oxiranylcarbinyl radical that undergoes rapid ring opening to give a highly reactive allyloxyl radical.
Keywords :
radicals and radical reactions , epoxides , fragmentation reactions , Polarity-reversal catalysis , addition reactions
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
