Title of article :
Doubly bridged biscalix[4]arene for homotropic and heterotropic allosteric effects on ion recognition
Author/Authors :
Nabeshima، نويسنده , , Tatsuya and Saiki، نويسنده , , Toshiyuki and Sumitomo، نويسنده , , Keiko and Akine، نويسنده , , Shigehisa، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
A novel host, which shows homotropic and heterotropic allostery for Na+ and Ag+ recognition, is constructed by utilizing a biscalix[4]arene skeleton bearing bipyridine and ester moieties. The host binds two Na+ ions, but the second binding to Na+ is considerably suppressed by the first Na+ ion bound in the other binding site.
Keywords :
Homotropic allostery , Ion recognition , Heterotropic allostery , bipyridine
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters