Title of article
Phosphonyl radical addition to enol ethers. The stereoselective synthesis of cyclic ethers
Author/Authors
Jessop، نويسنده , , Christopher M. and Parsons، نويسنده , , Andrew F. and Routledge، نويسنده , , Anne and Irvine، نويسنده , , Derek J.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
5095
To page
5098
Abstract
Addition of diethyl phosphite or diethyl thiophosphite to enol ethers, in the presence of a radical initiator, results in the regioselective synthesis of organophosphonate or phosphonothioate derivatives, respectively, under mild conditions. This method can be applied to the stereoselective formation of substituted tetrahydrofurans and tetrahydropyrans, on cyclisation of vinyl ethers bearing unsaturated side chains.
Keywords
Cyclisation , Phosphorus compounds , radicals and radical reactions
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1842238
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