Author/Authors :
Krompiec، نويسنده , , Stanislaw and Pigulla، نويسنده , , Mariola and Krompiec، نويسنده , , Micha? and Baj، نويسنده , , Stefan and Mrowiec-Bia?o?، نويسنده , , Julita and Kasperczyk، نويسنده , , Janusz، نويسنده ,
Abstract :
A highly selective rhodium and ruthenium catalyzed transformation of N-allylamines and N-allylamides to the corresponding 1-propenyl derivatives is described. Strong E-selectivity in the isomerization of allylamines was observed. The first catalytic system containing a transition metal complex for Z-selective isomerization of allylamides is presented. An application of siliceous mesoporous cellular foams for effective removal of the catalyst from the post-reaction mixture is described.
