Title of article
Stable free radical polymerization––acrylate alkoxyamine synthesis
Author/Authors
Johanna Lukkarila، نويسنده , , Julie L. and Hamer، نويسنده , , Gordon K. and Georges، نويسنده , , Michael K.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
3
From page
5317
To page
5319
Abstract
An efficient synthesis of the alkoxyamine containing a benzoyl peroxide fragment, one tert-butyl acrylate monomer unit and TEMPO via an oxymercuration reaction followed by an oxidative demercuration reaction is reported. The formation of significant amounts of an undesired reduced product with the latter reaction was overcome by using a milder reducing agent (NaBH3CN) than those (NaBH4, LiBH4) reported to work well in other systems.
Keywords
living-radical polymerization , Alkoxyamine synthesis , oxymercuration , demercuration
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1842331
Link To Document