Title of article :
Diastereoselectivity in the epoxidation of γ-hydroxy α,β-unsaturated esters: temperature and solvent effect
Author/Authors :
Rodr??guez، نويسنده , , Santiago and Vidal، نويسنده , , Alberto and Monroig، نويسنده , , Juan J. Rodriguez-Gonzalez، نويسنده , , Florenci V.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
The diastereoselectivity in the nucleophilic epoxidation of γ-hydroxy α,β-unsaturated compounds using lithium-tert-butylperoxide is highly dependent on the reaction solvent but not influenced by the temperature. The free hydroxyl is key for stereoselection.
Keywords :
Solvent effect , Unsaturated esters , diastereoselective epoxidation , Temperature influence
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
