Title of article
Reaction of a stable aminoarylcarbene with 2-chloroacrylonitrile: dearomatizing cyclization rather than cyclopropanation
Author/Authors
Solé، نويسنده , , Stéphane and Cattoën، نويسنده , , Xavier and Gornitzka، نويسنده , , Heinz and Bourissou، نويسنده , , Didier and Bertrand، نويسنده , , Guy، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
3
From page
5391
To page
5393
Abstract
The reaction of a stable aminoarylcarbene with 2-chloroacrylonitrile is reported. The resulting 1/1 adduct has been spectroscopically and structurally characterized. The initial Michael addition is not followed by cyclopropane formation but by a dearomatizing cyclization affording an original bicyclic structure.
Keywords
Carbenes , Cyclopropanation , Dearomatization
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1842368
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