Title of article
Color modulation for chemiluminescence of a dioxetane bearing a 3-(anthracen-9-yl)-5-hydroxyphenyl moiety induced by a complex of crown ether with potassium tert-butoxide
Author/Authors
Matsumoto، نويسنده , , Masakatsu and Kasai، نويسنده , , Daisuke and Yamada، نويسنده , , Kazutaka and Fukuda، نويسنده , , Natsuki and Watanabe، نويسنده , , Nobuko and Ijuin، نويسنده , , Hisako K. Ijuin، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
8079
To page
8082
Abstract
Color modulation was first observed for CT-induced chemiluminescent decomposition of a dioxetane bearing a 3-(anthracen-9-yl)-5-hydroxyphenyl induced by a complex of crown ether with potassium tert-butoxide in benzene system. The phenomenon is rationalized by conformational change of a biaryl moiety in the emitter, which is induced by steric interaction of anthryl and a plane of crown ether complex.
Keywords
1 , 2-Dioxetane , Chemiluminescence , Charge transfer , Color modulation , Crown ether
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1843662
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