Title of article
Diisobutylaluminium hydride (DIBAL-H) as a molecular scalpel: a new mechanistic proposal for a spiroketal rearrangement
Author/Authors
Meng، نويسنده , , Xiangbao and Zhang، نويسنده , , Yongmin and Sollogoub، نويسنده , , Matthieu and Sinaے، نويسنده , , Pierre، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
8165
To page
8168
Abstract
Taking advantage of our knowledge of the capacity of DIBAL-H to de-O-alkylate, we propose an alternative mechanism for a spiroketal rearrangement described by E. Suàrez. We also show that this proposal can account for the formation of the secondary product, whose original structure we propose to correct.
Keywords
spiroketal , Aluminium , Diisobutylaluminium hydride (DIBAL-H) , carbohydrates
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1843699
Link To Document