Title of article
Preparation of an aliphatic-substituted hypervalent iodine compound, tetracoordinate 1,2-iodoxetane 1-oxide, and its application to oxidation
Author/Authors
Kano، نويسنده , , Naokazu and Ohashi، نويسنده , , Masaki and Hoshiba، نويسنده , , Kazuhisa and Kawashima، نويسنده , , Takayuki، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
3
From page
8173
To page
8175
Abstract
A tetracoordinate 1,2-iodoxetane was prepared by the fluorination of a tricoordinate 1,2-iodoxetane with xenon difluoride followed by hydrolysis. The tetracoordinate 1,2-iodoxetane oxidized alcohols and a sulfide to the corresponding aldehydes and ketones, and a sulfoxide, respectively, in good to moderate yields under mild conditions.
Keywords
iodine , 2-Iodoxetane , 1 , Iodinane , Oxidation
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1843702
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