Title of article
Chemical fixation of CO2 with highly efficient ZnCl2/[BMIm]Br catalyst system
Author/Authors
Li، نويسنده , , Fuwei and Xiao، نويسنده , , Linfei and Xia، نويسنده , , Chungu and Hu، نويسنده , , Bin، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
8307
To page
8310
Abstract
The chemical fixation of CO2 with mono-substituted terminal epoxides or cyclohexene oxide to form cyclic carbonates under the ZnCl2/[BMIm]Br catalyst system without using additional organic solvents was achieved in excellent selectivity (>98%) and TOF (5410 h−1) and the catalyst could be used six times almost without losing its catalytic activity and selectivity. Besides, the pure cis-cyclic carbonate of cyclohexene oxide was obtained in this catalyst system.
Keywords
Catalyst reused , Pure cis-cyclic carbonate of cyclohexene oxide , epoxide , Chemical fixation of CO2
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1843762
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