Title of article
Synthesis of pyranosyl amidoximes by addition of amines to pyranosyl nitrile oxides
Author/Authors
Baker، نويسنده , , Kenneth W.J. and Horner، نويسنده , , Katherine S. and Moggach، نويسنده , , Stephen A. and Paton، نويسنده , , R. Michael and Smellie، نويسنده , , Iain A.S. Smellie، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
8913
To page
8916
Abstract
Addition of amines to pyranosyl nitrile oxides, generated by base-induced dehydrochlorination of the corresponding hydroximoyl chloride, affords pyranosyl N-alkyl/aryl-formamide oximes (41–90%). Reaction with amino acid esters yields the corresponding amidoximes and/or 3-pyranosyl-1,2,4-oxadiazin-6-ones. The structure of N-phenyl-C-(2,3,4-tri-O-acetyl-β-D-xylopyranosyl)formamide oxime was established by X-ray crystallography.
Keywords
C-Glycosides , Nitrile oxides , amidoximes , 1 , 2 , 4-Oxadiazin-6-ones
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1844005
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