Author/Authors :
Uno، نويسنده , , Hidemitsu and Moriyama، نويسنده , , Kana and Ishikawa، نويسنده , , Takayuki and Ono، نويسنده , , Noboru and Yahiro، نويسنده , , Hidenori، نويسنده ,
Abstract :
2,2′-Bi[-3(2H)-thiophenon]ylidene with two bicyclo[2.2.2]-octadiene moieties was quantitatively converted to thioindigo by the retro-Diels–Alder reaction. The thioindigo solid obtained from the precursor had the P21/c structure which was different from the commercial thioindigo samples (P21/n).
Keywords :
Thioindigo , Polymorphism , Soluble precursor , Retro-Diels–Alder reaction
