Title of article
Fluoride-mediated phosphination of alkenes and alkynes by silylphosphines
Author/Authors
Hayashi، نويسنده , , Minoru and Matsuura، نويسنده , , Yutaka W. Watanabe، نويسنده , , Yutaka، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
3
From page
9167
To page
9169
Abstract
Regioselective phosphination of carbon–carbon unsaturated bonds by a fluoride-mediated reaction of silylphosphines is described. Alkenes and alkynes having a directing group, such as an aromatic or a carbonyl group, reacted to form a carbon–phosphorus bond under mild conditions. When an anhydrous fluoride source was applied in the presence of an electrophile, the corresponding three-component coupling product was obtained.
Keywords
three-component coupling , Silylphosphine , Michael addition , Phosphination
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1844111
Link To Document