Title of article
Ene reactions of acyl nitroso intermediates with alkenes and their halocyclization
Author/Authors
Fakhruddin، نويسنده , , Ahmad and Iwasa، نويسنده , , Seiji and Nishiyama، نويسنده , , Hisao and Tsutsumi، نويسنده , , Kazuo، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
9323
To page
9326
Abstract
Highly reactive acyl nitroso intermediates were formed in situ by transition metals-catalyzed hydrogen peroxide oxidation of hydroxamic acids 1a–b and these transient species trapped with alkenes 2a–c to afford the corresponding ene products 3a–d and 4b up to 91% yield, and halocyclization of 3d gave substituted oxazolidinone 5a in 77% yield.
Keywords
Acyl nitroso , Halocyclization , Ruthenium , Ene reaction , iridium , Copper , Hydrogen peroxide
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1844170
Link To Document