Author/Authors :
Clark، نويسنده , , J. Stephen and Clarke، نويسنده , , Melanie-Rose and Clough، نويسنده , , John and Blake، نويسنده , , Alexander J. and Wilson، نويسنده , , Claire، نويسنده ,
Abstract :
Enantioselective symmetrising–desymmetrising allylic oxidation of racemic bridged bicyclic alkenes using an asymmetric copper-catalysed Kharasch–Sosnovsky reaction has been explored. Good yields and reasonable levels of induction (up to 70% ee) have been obtained using carbocyclic systems as substrates.
Keywords :
Catalytic , Oxidation , enantioselective , Alkene
