Title of article
Asymmetric allylic oxidation of bridged-bicyclic alkenes using a copper-catalysed symmetrising–desymmetrising Kharasch–Sosnovsky reaction
Author/Authors
Clark، نويسنده , , J. Stephen and Clarke، نويسنده , , Melanie-Rose and Clough، نويسنده , , John and Blake، نويسنده , , Alexander J. and Wilson، نويسنده , , Claire، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
9447
To page
9450
Abstract
Enantioselective symmetrising–desymmetrising allylic oxidation of racemic bridged bicyclic alkenes using an asymmetric copper-catalysed Kharasch–Sosnovsky reaction has been explored. Good yields and reasonable levels of induction (up to 70% ee) have been obtained using carbocyclic systems as substrates.
Keywords
Catalytic , Oxidation , enantioselective , Alkene
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1844220
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