• Title of article

    Synthesis of 2-(ethylsulfanyl)aniline derivatives through the unexpected ring opening of N-substituted-2(3H)-benzothiazolones

  • Author/Authors

    Lebegue، نويسنده , , Nicolas and Charrier، نويسنده , , Gaetan and Carato، نويسنده , , Pascal and Yous، نويسنده , , Saïd and Berthelot، نويسنده , , Pascal، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2004
  • Pages
    3
  • From page
    9509
  • To page
    9511
  • Abstract
    The decarbalkoxylations of disubstituted geminal diesters by water–DMSO with added salts (KCN or NaCN) is a convenient preparative route leading to the corresponding monoesters. Herein, we described an efficient and very simple methodology for the preparation of 2-(ethylsulfanyl)aniline derivatives through the unexpected ring opening of the corresponding N-substituted-2(3H)-benzothiazolones in the presence of disubstituted geminal diester, KCN, and water–DMSO.
  • Keywords
    2-(Ethylsulfanyl)aniline , Ring opening , N-Substituted-2-(3H)-benzothiazolones , Krapcho method
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2004
  • Journal title
    Tetrahedron Letters
  • Record number

    1844243