Title of article
The unusual course of the high-pressure reaction of 1,10-diaza-[18]-crown-6 with α,ω-diiodo ethers
Author/Authors
Tarnowska، نويسنده , , Aldona and Tarnowski، نويسنده , , Piotr and Jurczak، نويسنده , , Janusz، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
9553
To page
9556
Abstract
Simple 1,10-diaza-[18]-crown-6 reacts smoothly with di(2-indoethyl)ether under high-pressure (10 kbar) to give a bis-quaternary spiro salt as a major product, whereas the analogous reaction with 1,8-diiodo-3,6-dioxaoctane leads to the expected precursor of a [2.2.2] cryptand.
Keywords
high pressure , Double quaternization , Spiro salts , Macrocycles
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1844261
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