• Title of article

    The unusual course of the high-pressure reaction of 1,10-diaza-[18]-crown-6 with α,ω-diiodo ethers

  • Author/Authors

    Tarnowska، نويسنده , , Aldona and Tarnowski، نويسنده , , Piotr and Jurczak، نويسنده , , Janusz، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2004
  • Pages
    4
  • From page
    9553
  • To page
    9556
  • Abstract
    Simple 1,10-diaza-[18]-crown-6 reacts smoothly with di(2-indoethyl)ether under high-pressure (10 kbar) to give a bis-quaternary spiro salt as a major product, whereas the analogous reaction with 1,8-diiodo-3,6-dioxaoctane leads to the expected precursor of a [2.2.2] cryptand.
  • Keywords
    high pressure , Double quaternization , Spiro salts , Macrocycles
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2004
  • Journal title
    Tetrahedron Letters
  • Record number

    1844261