Author/Authors :
Karatsu، نويسنده , , Takashi and Miyazaki، نويسنده , , Yoshinori and Shimura، نويسنده , , Yuuki and Okayasu، نويسنده , , Akinori and Suzuki، نويسنده , , Takaaki and Higashi، نويسنده , , Masaki and Yagai، نويسنده , , Shiki and Kitamura، نويسنده , , Akihide، نويسنده ,
Abstract :
The behavior of the 3-alkylidene-1-pyrazoline radical cations generated by photoinduced electron transfer reactions was examined. The nitrogen-retained radical cations have been detected using laser flash photolysis. The photochemical products indicate that E/Z isomerization, intramolecular cyclization, and solvent addition (acetonitrile) occurred.
Keywords :
radical cation , pyrazoline , Laser flash photolysis , photoinduced electron transfer
