Title of article
Regioselective hydrosilylation of terminal acetylenes via acetylene–Co2(CO)4dppm complex: effects of the ligands in acetylenedicobalt complex
Author/Authors
Tojo، نويسنده , , Shingo and Isobe، نويسنده , , Minoru، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
381
To page
384
Abstract
The regioselective hydrosilylation of the acetylenedicobalt complex on the terminal acetylene with special reference to the ligands to produce a vinylsilane is described. It was found that the use of the ligands exchanged dicobalttetracarbonyl bis(diphenylphosphino)methane complex dramatically changed the regioselectivity compared to the corresponding dicobalthexacarbonyl complex.
Keywords
Hydosilylation , Acetylenedicobalt complex , Vinylsilane
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1844461
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