• Title of article

    Stereoselective alkylation of thiacalix[4]arenes

  • Author/Authors

    Himl، نويسنده , , Michal and Pojarovل، نويسنده , , Michaela and Stibor، نويسنده , , Ivan and S‎kora، نويسنده , , Jan and Lhotلk، نويسنده , , Pavel، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2005
  • Pages
    4
  • From page
    461
  • To page
    464
  • Abstract
    A direct tetraalkylation of thiacalix[4]arenes using procedures well established in ‘classical’ calixarene chemistry usually gives the 1,3-alternate conformers as the main product (n-PrI/K2CO3/acetone) while the cone conformers are obtained only in very poor yields (n-PrI/NaH/DMF). Surprisingly, the so far almost inaccessible cone conformers can be prepared in high yields using the two-step procedure: dialkylation–dialkylation, opening the way for their further utilisation in supramolecular chemistry.
  • Keywords
    Calixarene , Alkylation , Conformations
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2005
  • Journal title
    Tetrahedron Letters
  • Record number

    1844491

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1844491