Title of article
Stereoselective synthesis of substituted dienes by the double ortho ester Claisen rearrangement
Author/Authors
Hong، نويسنده , , Suk-pyo and Yoon، نويسنده , , Sung-jun and Yu، نويسنده , , Byung-chan، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
779
To page
782
Abstract
This letter shows the highly stereoselective synthesis of substituted (E)-1,3-dienes from substituted propargylic diols via the double ortho ester Claisen rearrangement. The cyclohexyl-substituted diene undergoes thermal Diels–Alder cycloaddition with maleic anhydride to produce the corresponding bicyclic diester in highly stereoselective manner.
Keywords
The double ortho ester Claisen rearrangement , Substituted propargylic diols , (E)-1 , 3-dienes , Diels–Alder cycloaddition
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1844620
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