Author/Authors :
Rajakumar، نويسنده , , Perumal and Dhanasekaran، نويسنده , , Manickam and Selvanayagam، نويسنده , , Sivashanmugam and Rajakannan، نويسنده , , Venkatachalam and Velmurugan، نويسنده , , Devadasan and Ravikumar، نويسنده , , Krishnan، نويسنده ,
Abstract :
A one-pot synthesis of structurally isomeric tetrathiacyclophanes through four-centre coupling reactions of suitable bromides and thiols is reported. The structures of the isomers were confirmed by spectroscopy and XRD analysis. Single crystal X-ray analysis reveals interestingly shaped molecular structures with large cavities.
Keywords :
Isomeric cyclophanes , Pyridinophanes , One-pot , Four-centre , SELF-ASSEMBLY