Title of article :
Selective oxidation of benzylic or allylic hydroxyl group of sec-1,2-diols
Author/Authors :
Peng، نويسنده , , Kun and Chen، نويسنده , , Fuxin and She، نويسنده , , Xuegong and Yang، نويسنده , , Chunhui and Cui، نويسنده , , Yuxin and Pan، نويسنده , , Xinfu، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
A mild and efficient method to selectively oxidize chiral sec-1,2-diols has been developed, which demonstrates that 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) can selectively oxidize benzylic or allylic hydroxyl group of sec-1,2-diols under ultrasound wave promotion. The configuration of the adjacent chiral center is retained.
Keywords :
DDQ , Ultrasound wave , Vicinal position , Selective oxidation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
