• Title of article

    Enantioselective Morita–Baylis–Hillman (MBH) reaction promoted by a heterobimetallic complex with a Lewis base

  • Author/Authors

    Matsui، نويسنده , , Katsuya and Takizawa، نويسنده , , Shinobu and Sasai، نويسنده , , Hiroaki، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2005
  • Pages
    4
  • From page
    1943
  • To page
    1946
  • Abstract
    A new double-activation catalysis is presented for the Morita–Baylis–Hillman (MBH) reaction of an α,β-unsaturated ketone and an aldehyde by the combined use of a heterobimetallic asymmetric complex and tributylphosphine ((n-Bu)3P) to afford the α-methylene-β-hydroxy ketone with up to 99% ee.
  • Keywords
    Morita–Baylis–Hillman (MBH) reaction , Double-activation
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2005
  • Journal title
    Tetrahedron Letters
  • Record number

    1845109