• Title of article

    Chromium(III) catalyzed synthesis of allenes from propargyl derivatives via a carbometalation–elimination sequence

  • Author/Authors

    Molander، نويسنده , , Gary A. and Sommers، نويسنده , , Erin M.، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2005
  • Pages
    5
  • From page
    2345
  • To page
    2349
  • Abstract
    The syn-carbometalation/syn-elimination of propargyl substrates to form allenes has been achieved using cationic chromium(III) catalysts activated by alkylaluminums. The mechanism and scope of this transformation are presented.
  • Keywords
    Allenes , Propargylic compounds , Chromium(III) complexes
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2005
  • Journal title
    Tetrahedron Letters
  • Record number

    1845258